V J Menon
Articles written in Pramana – Journal of Physics
Volume 69 Issue 3 September 2007 pp 423-433 Research Articles
Gauss law constraints on Debye–Hückel screening
Ritesh Kumar Dubey V J Menon Madhukar Mishra Mukesh Kumar Pandey B K Patra
We demand that the Gauss law at the edge must be obeyed by the electric potential $\phi(r)$ generated within a neutral plasma/electrolyte of strictly finite size by the introduction of a test charge $q_{b}$. Our proposal has the nice features that total ionic numbers are conserved, the point-Coulomb behaviour of $\phi(r)$ is guaranteed at short-distance, and accumulation of induced charges near the centre and the surface can be demonstrated rigorously. In contrast, the standard Debye–Hückel potential $\phi_{D}(r)$ applicable to unbounded plasma has the strange features that the Gauss law cannot be obeyed at the plasma's edge, total ionic numbers themselves are altered, the short-distance Coulomb behaviour has to be imposed by hand, and induced charge appearance at the surface cannot be built-in.
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