Sayan Bhattacharyya
Articles written in Pramana – Journal of Physics
Volume 70 Issue 2 February 2008 pp 367-373 Contributed papers
Observation of exchange bias and spin-glass-like ordering in 𝜀-Fe2.8Cr0.2N nanoparticles
N S Gajbhiye Sayan Bhattacharyya Sachil Sharma
Nanoparticles of 𝜀-Fe2.8Cr0.2N system exhibit the exchange bias phenomenon due to the exchange coupling of the spins of the antiferromagnetic (AF) oxide/oxynitride surface layer and the ferromagnetic (FM) nitride core. Exchange bias is observed at 10 K both in the absence and presence of cooling field. Due to the interface disorder, a mixture of parallel and anti-parallel/perpendicular coupling of the AF and FM spins is observed. The roughness of AF-FM interface induces disorder due to the random exchange anisotropy. The saturation magnetization is also found to be drastically lowered as compared to parent 𝜀-Fe3N. Below 58 K, the broad peak ($T_{E} \cong T_{f}$) in zero-field cooled (ZFC) magnetization curves indicates the presence of unidirectional anisotropy and spin-glass-like ordering, that arises from the freezing of localized frustrated spins.
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