Raman scattering investigation of phase transition in the ferroelectric Ba0.95Ca0.05TiO3 is reported. The results suggest onset of significant dynamic disorder at 105°C. This corroborates findings of recent structural study regarding large positional disorder associated with Ti and O1 atoms well below the tetragonal to cubic transition temperature (∼150°C).
Pramana – Journal of Physics
Volume 96, 2022 All articles Continuous Article Publishing mode
