R C Agnihotri
Articles written in Pramana – Journal of Physics
Volume 17 Issue 4 October 1981 pp 361-368 Chemical Physics
Ising model formalism developed for order-disorder transition in poly-peptides has been modified for the study of order-order transition in a macromolecular system. A two-state theory is developed and applied to poly-L-proline I and II. Various transition curves for different chain lengths are obtained as a function of solvent composition. Transition curves and crossing point for a solvent system are in excellent agreement with the experimental data on poly-L-proline.
Volume 19 Issue 1 July 1982 pp 43-49 Statistical Physics
Dipalmitoyllecithin (DPL) shows an order ← → disorder pressure transition which is neither of first order nor of second order but can be treated as a fractional order (3/2 order) transition. The Ising model formalism is adopted for the study of such a system. A suitable equilibrium constant is defined which generates a 3/2 order transition. Transition curves are obtained and compared with the experimental curves of Liu and Kay. Reverse transition curves are also obtained and the system exhibits hysteresis effect. An approximate expression connecting transition pressures at different temperatures is obtained and the calculated and the experimental values are in good agreement.
Volume 93 | Issue 6
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