R Pragash
Articles written in Pramana – Journal of Physics
Volume 77 Issue 6 December 2011 pp 1119-1126
Spectroscopic properties of $Pr^{3+}$-doped erbiumoxalate crystals
R Pragash N V Unnikrishnan C Sudarsanakumar
Spectroscopic properties of praseodymium ions-doped erbium oxalate ($Er_2(C_2O_4)_3 \cdot nH_2O$) crystals have been investigated. The crystals were grown by hydro silica gel method under suitable pH conditions and by single diffusion method. The well-grown crystals are bright and transparent. The dark green colour of these crystals changes with the variation of the concentrations of the dopant ions. The absorption spectra have been measured in the region 200–800 nm at room temperature. Judd–Ofelt intensity parameters for f–f transitions of the $Pr^{3+}$ ions have been determined as $\Omega_2 = 166.7$, $\Omega_4 = 1.103$ and $\Omega_6 = 2.898$. Analyses of the absorption spectra also show a possible energy transfer from the host material to the dopant.
Volume 96, 2022
All articles
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode
© 2021-2022 Indian Academy of Sciences, Bengaluru.