Articles written in Pramana – Journal of Physics
Volume 75 Issue 6 December 2010 pp 1209-1214 Conributed Papers
Polyacrylamide (PAAm) hydrogels immersed in water and aqueous NaCl solutions were investigated for their structure and dynamics using static and quasi-elastic laser light scattering (QELS) techniques. Ensemble-averaged electric field correlation function $f (q, t)$ obtained from the non-ergodic analysis of intensity-autocorrelation function for PAAm gel immersed in water and in 5 M NaCl showed an exponential decay to a plateau with an initial decay followed by saturation at long times. The value of the plateau was found to depend on NaCl concentration and was higher than that of water. Collective diffusion coefficient, 𝐷, of the polymer network of the hydrogel immersed in water and in different concentrations of NaCl was determined by analysing $f (q, t)$. The measured diffusion coefficient showed linear decrease with increase in concentration of NaCl. The characteristic network parameters were obtained by analyzing $f (q, t)$ with harmonically bound Brownian particle model and from static light scattering studies.
Volume 79 Issue 3 September 2012 pp 457-469
Swelling kinetics of water-swollen polyacrylamide (PAAm) hydrogels (WSG) was investigated in various concentrations of aqueous NaCl by macroscopic swelling measurements. For lower concentration of NaCl, WSG showed exponential swelling whereas at higher concentration of NaCl it underwent deswelling at short times and exponential swelling at long times. From these studies, collective diffusion coefficient, 𝐷, of the polymer network and polymer–solvent interaction parameter, 𝜒 , were calculated and found to decrease with increase in [NaCl]. Collective diffusion coefficients measured from dynamic light scattering (DLS) and that obtained from macroscopic swelling measurements are found to agree well. Measured ensemble-averaged dynamic structure factor $f (q, t)$ for WSG and salt-swollen gels (SSG) showed an initial decay followed by a plateau at long times and it can be described by harmonically bound Brownian particle (HBBP) model. Enhanced scattering intensity at low scattering angles using static light scattering (SLS) measurements revealed the presence of inhomogeneities in PAAm gels. The reasons for increased scattering intensity of SSG over WSG gel and the linear decrease of 𝐷 with increase in NaCl concentration are explained.
Volume 96, 2022
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