K S V Santhanam
Articles written in Pramana – Journal of Physics
Volume 5 Issue 6 December 1975 pp 339-348 Chemical Physics
The effect of deuteration on the electrochemiluminescence (ECL) efficiencies of the mixed systems containing anthracene or phenathrene has been examined using the single light pulse in the double potential programme. Deuteration of anthracene or phenanthrene decreases the ECL efficiencies by factors of 1·2–16·0. This decrease appears to arise from the quenching of the triplets by radical ions in solution. The quenching factors are estimated by using Marcus theory of electron transfer reactions.
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