I K Gopalakrishnan
Articles written in Pramana – Journal of Physics
Volume 63 Issue 2 August 2004 pp 277-283
Sphere-to-rod transition of triblock copolymer micelles at room temperature
R Ganguly V K Aswal P A Hassan I K Gopalakrishnan J V Yakhmi
A room temperature sphere-to-rod transition of the polyethylene oxide-polypropylene oxide-polyethylene oxide-based triblock copolymer, (PEO)20(PPO)70 (PEO)20 micelles have been observed in aqueous medium under the influence of ethanol and sodium chloride. Addition of 5–10% ethanol induces a high temperature sphere-to-rod transition of the micelles, which is brought to room temperature upon addition of NaCl. The inference about the change in the shape of the micelles has been drawn from small-angle neutron scattering (SANS) and viscosity studies.
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