Articles written in Pramana – Journal of Physics
Volume 66 Issue 2 February 2006 pp 435-446
Speed of sound and densities of the ternary mixture 2-propanol + diethyl ether + n-hexane and also the binary mixtures 2-propanol + diethyl ether and 2-propanol + n-hexane have been measured at the entire composition range at 298.15 K. The excess isentropic compressibilities and the excess speed of the sound have been calculated from experimental densities and speed of sound. These excess properties of the binary mixtures were fitted to Redlich-Kister equation, while the Cibulka’s equation was used to fit the values related to the values to the ternary system. These excess properties have been used to discuss the presence of significant interactions between the component molecules in the binary mixtures and also the ternary mixtures.
Speed of sound of the binary mixtures and the ternary mixture have been compared with calculated values from free length theory (FLT), collision factor theory (CFT), Nomoto’s relation (NR), Van Deal’s ideal mixing relation (IMR) and Junjie’s relation (JR). The results are used to compare the relative merits of these theories and relations in terms of the root mean square deviation relative (RMSDr).
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