• A H Venkatesh

      Articles written in Pramana – Journal of Physics

    • A simple white beam neutron diffraction technique

      A H Venkatesh K R Rao

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      White beam neutron diffraction by time-of-flight (TOF) technique has been studied over a number of years as it is believed to be the most convenient method to investigate solids in a fixed geometry. This technique needs a pulsed neutron source and a suitable multichannel, analysing system. The entire system is in general, mechanically quite intricate and expensive.

      We have investigated an alternative technique to achieve the end result of a constant geometry around the diffracting sample. This involves the use of a single crystal as an analyser to study diffraction pattern from the sample bathed in a white beam and diffracting at any fixed scattering angle. In this paper we report the results of our investigations and have compared this technique with other diffraction techniques. Taking Si, KCl and KNO3 as typical specimens we have illus. trated the results of our technique and we find that the results are comparable to those obtained by conventional neutron diffraction and TOF diffraction. The technique is simple in mechanical design and data acquisition. It can be easily adapted for high pressure diffraction which is being attempted.

    • Inelastic neutron scattering from and lattice dynamics of α-KNO3

      K R Rao S L Chaplot P K Iyengar A H Venkatesh P R Vijayaraghavan

      More Details Abstract Fulltext PDF

      Coherent inelastic neutron scattering techniques are employed to measure several branches of the phoon dispersion relation in KNO3 in its orthorhombic (α-phase or phase II) form at room temperature. Group theoretical selection rules for external modes of the crystal have been used in the measurements along the three symmetry directions Σ(ξ00), Δ(0ξ0) and Λ(00ξ).

      Theoretical investigation of the lattice dynamics of the crystal is carried out on the basis of a rigid molecular-ion model using the external mode formalism. A two-body potential consisting of the Coulombic interaction and the Born-Mayer type short range interaction is assumed. The effective charges and radii of different atoms are determined by applying the stability criterion for the crystal. Dispersion curves are calculated, representation by representation, making use of group theoretical information. Comparison of theoretical results with experimental information on elastic constants, optical data and neutron results are made. Agreement between theoretical and the various experimental results may be considered very satisfactory.

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