V K Banakar
Articles written in Journal of Earth System Science
Volume 114 Issue 1 February 2005 pp 51-61
Eight ferromanganese crusts (Fe-Mn crusts) with igneous and sedimentary substrates collected at different water depths from the Afanasiy-Nikitin Seamount are studied for their bulk major, minor and rare earth element composition. The Mn/Fe ratios < 1.5 indicate the hydrogenetic accretion of the Fe-Mn hydroxides. These Fe-Mn crusts are enriched in Co (up to 0.9%, average ∼ 0.5%) and Ce. The Ce-content is the highest reported so far (up to 3763 ppm, average ∼ 2250 ppm) for global ocean seamount Fe-Mn crusts. In spite of general similarity in the range of major, minor, and strictly trivalent rare earth element composition, the dissimilarity between the present Fe-Mn crusts and the Pacific seamount Fe-Mn crusts in Co and Ce associations with major mineral phases indicates inter-oceanic heterogeneity and region-specific conditions responsible for their enrichment. The decrease in Ce-anomaly (from ∼ 8 to ∼ 1.5) with increasing water depth (from ∼ 1.7 km to ∼ 3.2 km) might suggest that the modern intermediate depth low oxygen layer was shifted and sustained at a deeper depth for a long period in the past.
Volume 116 Issue 1 February 2007 pp 3-13
The major element relationships in ferromanganese (Fe-Mn) crusts from Afanasiy-Nikitin seamount (ANS), eastern equatorial Indian Ocean, appear to be atypical. High positive correlations (𝑟 = 0.99) between Mn/Co and Fe/Co ratios, and lack of correlation of those ratios with Co, Ce, and Ce/Co, indicate that the ANS Fe-Mn crusts are distinct from Pacific seamount Fe-Mn crusts, and reflect region-specific chemical characteristics. The platinum group elements (PGE: Ir, Ru, Rh, Pt, and Pd) and Au in ANS Fe-Mn crusts are derived from seawater and are mainly of terrestrial origin, with a minor cosmogenic component. The Ru/Rh (0.5-2) and Pt/Ru ratios (7-28) are closely comparable to ratios in continental basalts, whereas Pd/Ir ratios exhibit values (> 2) similar to CI-chondrite (∼1). The chondrite-normalized PGE patterns are similar to those of igneous rocks, except that Pd is relatively depleted. The water depth of Fe-Mn crust formation appears to have a first-order control on both major element and PGE enrichments. These relationships are defined statistically by significant (𝑟 < 0.75) correlations between water depth and Mn/Co, Fe/Co, Ce/Co, Co, and the PGEs. Fractionation of the PGE-Au from seawater during colloidal precipitation of the major-oxide phases is indicated by well-defined linear positive correlations (𝑟 < 0.8) of Co and Ce with Ir, Ru, Rh, and Pt; Au/Co with Mn/Co; and by weak or no correlations of Pd with water depth, Co-normalized major-element ratios, and with the other PGE (𝑟 $mt; 0.5). The strong enrichment of Pt (up to 1 ppm) relative to the other PGE and its positive correlations with Ce and Co demonstrate a common link for the high concentrations of all three elements, which likely involves an oxidation reaction on the Mn-oxide and Fe-oxyhydroxide surfaces. The documented fractionation of PGE-Au and their positive association with redox sensitive Co and Ce may have applications in reconstructing past-ocean redox conditions and water masses.
Volume 117 Issue 2 April 2008 pp 113-119
Three sediment cores in a north–south transect (3°N to 13°S) from different sediment types of the Central Indian Ocean Basin (CIOB) are studied to understand the possible relationship between magnetic susceptibility (𝜒) and Al, Fe, Ti and Mn concentrations. The calcareous ooze core exhibit lowest 𝜒 (12.32 × 10-7m3 kg−1), Al (2.84%), Fe (1.63%) and Ti (0.14%), terrigenous clay core with moderate 𝜒 (29.9 × 10-7 m3 kg−1) but highest Al (6.84%), Fe (5.20%) and Ti (0.44%), and siliceous ooze core with highest 𝜒 (38.06 × 10-7 m3 kg−1) but moderate Al (4.49%), Fe (2.80%) and Ti (0.19%) contents. The distribution of 𝜒 and detrital proxy elements (Al, Fe, and Ti) are identical in both calcareous and siliceous ooze. Interestingly, in terrigenous core, the behaviour of 𝜒 is identical to only Ti content but not with Al and Fe suggesting possibility of Al and Fe having a non-detrital source.
The occurrence of phillipsite in terrigenous clay is evident by the Al-K scatter plot where trend line intersects K axis at more than 50% of total K suggesting excess K in the form of phillipsite. Therefore, the presence of phillipsite might be responsible for negative correlation between 𝜒 and Al (𝑟 = −0.52). In siliceous ooze the strong positive correlations among 𝜒, Alexc and Feexc suggest the presence of authigenic Fe-rich smectite. High Mn content (0.5%) probably in the form of manganese micronodules is also contributing to 𝜒 in both calcareous and siliceous ooze but not in the terrigenous core where mean Mn content (0.1%) is similar to crustal abundance. Thus, 𝜒 systematically records the terrigenous variation in both the biogenic sediments but in terrigenous clay it indirectly suggests the presence of authigenic minerals.
Volume 123 Issue 1 February 2014 pp 33-47
The Afanasy Nikitin seamount (ANS) is a major structural feature (400 km-long and 150 km-wide) in the Central Indian Basin, situated at the southern end of the so-called 85°E Ridge. Combined analyses of new multibeam bathymetric, seismic reflection and geochronological data together with previously described magnetic data provide new insights into the growth of the ANS through time, and its relationship with the 85°E Ridge. The ANS comprises a main plateau, rising 1200 m above the surrounding ocean floor (4800 m), and secondary elevated seamount highs, two of which (lie at 1600 and 2050 m water depths) have the morphology of a guyot, suggesting that they were formed above or close to sea-level. An unbroken sequence of spreading anomalies 34 through 32n.1 identified over the ANS reveal that the main plateau of the ANS was formed at 80–73 Ma, at around the same time as that of the underlying oceanic crust. The 40Ar/39Ar dates for two basalt samples dredged from the seamount highs are consistent, within error, at 67 Ma. These results, together with published results of late Cretaceous to early Cenozoic Indian Ocean plate reconstructions, indicate that the Conrad Rise hotspot emplaced both the main plateau of the ANS and Conrad Rise (including the Marion Dufresne, Ob and Lena seamounts) at 80–73 Ma, close to the India–Antarctica Ridge system. Subsequently, the seamount highs were formed by late-stage volcanism c. 6–13 Myr after the main constructional phase of the seamount plateau. Flexural analysis indicates that the main plateau and seamount highs of the ANS are consistent with Airy-type isostatic compensation, which suggest emplacement of the entire seamount in a near spreading-center setting. This is contrary to the flexural compensation of the 85°E Ridge further north, which is interpreted as being emplaced in an intraplate setting, i.e., 25–35 Myr later than the underlying oceanic crust. Therefore, we suggest that the ANS and the 85°E Ridge appear to be unrelated as they were formed by different mantle sources, and that the proximity of the southern end of the 85°E Ridge to the ANS is coincidental.