• Madhuparna Roy

      Articles written in Journal of Earth System Science

    • Mineral shock signatures in rocks from Dhala (Mohar) impact structure, Shivpuri district, Madhya Pradesh, India

      Madhuparna Roy Pradeep Pandey Shailendra Kumar P S Parihar

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      A concrete study combining optical microscopy, Raman spectroscopy and X-ray diffractometry, was carried out on subsurface samples of basement granite and melt breccia from Mohar (Dhala) impact structure, Shivpuri district, Madhya Pradesh, India. Optical microscopy reveals aberrations in the optical properties of quartz and feldspar in the form of planar deformation feature-like structures, lowered birefringence and mosaics in quartz, toasting, planar fractures and ladder texture in alkali feldspar and near-isotropism in bytownite. It also brings to light incidence of parisite, a radioactive rare mineral in shocked granite. Raman spectral pattern, peak positions, peak widths and multiplicity of peak groups of all minerals, suggest subtle structural/crystallographic deviations. XRD data further reveals minute deviations of unit cell parameters of quartz, alkali feldspar and plagioclase, with respect to standard α-quartz, high- and low albite and microcline. Reduced cell volumes in these minerals indicate compression due to pressure. The c0/a0 values indicate an inter-tetrahedral angle roughly between 120o and 144o, further pointing to a possible pressure maxima of around 12 GPa. The observed unit cell aberration of minerals may indicate an intermediate stage between crystalline and amorphous stages, thereby, signifying possible overprinting of decompression signatures over shock compression effects, from a shock recovery process.

    • Structural and luminescent characterisation of uraniferous fluorapatite and haematite associated with phosphatic rocks of the Bijawar group in Sagar District, Madhya Pradesh (India)

      Pragya Pandit Shailendra Kumar Pargin Bangotra Rohit Mehra Manoj Mohapatra Madhuparna Roy Singh A K

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      The structural and spectroscopic characteristics of phosphatic ferruginous shale samples from the Bijawar Group rocks from Sagar District of Madhya Pradesh (India) have been probed for identification of uranium species. Fluorapatite (Ca$_{5}$(PO$_{4}$)$_{3}$F, FAP) and haematite ($\alpha$-Fe$_{2}$O$_{3}$) were identified as the main phases in the separated mineral concentrates. The photoluminescence (PL) and X-ray absorption near edge spectroscopy (XANES) studies pointed to a strong experimental evidence of both U(IV) and U(VI) oxidation states in the mineral concentrate portion obtained from the same parent host rock. The PL spectrum has confirmed the charge transfer (f–d) transition bands in UV and near-UV regions with emission peaks at ca. 290, 313, 336, 399 and 416 nm, which has been attributed to the substitution of Ca$^{2+}$ ions by U(IV) in FAP and broad structureless emission due to stabilisation of U(VI) as UO$_6^{6-}$ in haematite. Time-resolved spectroscopy studies have revealed biexponential decay components lasting 2–5 ns for U(IV) species and 10 $\mu$s for U(VI) species. These characterisations revealed the fundamental information about the oxidation state and form of uranium in this region. Remediation measures for the Bijawar region are also suggested.

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