Articles written in Journal of Earth System Science
Volume 111 Issue 2 June 2002 pp 87-101
Syngenetic carbonate nodules constitute an interesting feature of the glaciogene sediments of various Talchir basins in peninsular India. Petrographic, cathodoluminescence and sedimentary results suggest that many of these nodules contain primary carbonate precipitates whose geochemical signatures can be used for determining environment of deposition and provenance of the sediments and drainage source. Several nodules were collected from Gondwana basins of east-central India and analyzed for stable carbon and oxygen isotope ratios, REE and trace element composition, and Sr isotope ratio. The mean 𝛿18O and 𝛿13C values of the calcites in the nodules are — 19.5‰ and -9.7‰ (w.r.t. PDB) respectively suggesting a freshwater environment (probably lacustrine) for formation of these objects. Trace element ratios (Eu/Eu∗ and La/Yb) of the nodule samples show that the source of the sediments in the Damodar valley basin was the granites, gneisses and intrusives in the Chotanagpur region. The sediments in the Mahanadi valley were derived from granulites, charnockites and granites of the eastern ghat region. The Sr concentration of the carbonate phase of the nodules is low, ranging from 10-60 ng/g . The 87Sr/86Sr ratios of the samples from the west Bokaro basin and Ramgarh basin vary from 0.735 to 0.748 (mean: 0.739) and from 0.726 to 0.733 (mean: 0.730) respectively. These values are consistent with our proposition that water of these basins drained through the granitic rocks of the Chotanagpur region. In contrast, the 87Sr/86Sr ratios of the samples from the Talchir basin (Type area) of Mahanadi valley vary from 0.718 to 0.723 (mean: 0.719). These 87Sr/86Sr ratios are close to those of the granulites in the adjoining eastern ghat belt suggesting that area as the drainage source.
Volume 113 Issue 4 December 2004 pp 649-665
Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼ 0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; (ΣHREE)N ∼ 2–3 times chondrite, (Gd/Yb)N ∼ 1). The εNd(t) values vary from +1.23 to -3.27 whereas δ18O values vary from +3.16‰ to +5.29‰ (average +3.97‰±0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (± silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable εNd, low Sri(0.702) and low δ18O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.
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