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- Volume 132 All articles Published: 5 September 2020 Article ID 0120
  
  A novel reaction of 2-phenacyl mercaptoimidazole with acetic anhydride: formation of an imidazothiazole with loss of a phenyl group
  
  SHASHIPRABHA K NAGARAJAN SAJESH P THOMAS SURESH P NAYAK K SUNDARRAJA RAO K SHRIDHARA T N GURU ROW
  
  More Details Abstract Fulltext PDF
  
  Attempted cyclodehydration of phenacyl mercaptoimidazole hydrobromide with acetic anhydride gave an abnormal product lacking the phenyl group. The molecular structure is confirmed using X-ray crystal structure studies. Phenacyl mercaptobenzimidazole hydrobromide behaved similarly. Analysis of crystalstructure revealed an intermolecular S…Br chalcogen bonding interaction

Journal of Chemical Sciences

Volume 134, 2022
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