• VIKAS D GHULE

      Articles written in Journal of Chemical Sciences

    • 2,4,6-tris[bis(1H-tetrazol-5-yl)amino]-1,3,5-triazine as a nitrogen-rich material

      MUDDAMARRI HANUMANTHA RAO VIKAS D GHULE KRISHNAMURTHI MURALIDHARAN

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      This paper describes the synthesis, characterization and energetic properties of tetrazole and triazine-based thermally stable, insensitive nitrogen-rich high energy density materials of N, N’, N”-(1,3,5- triazine-2,4,6-triyl) tris(N-cyanocyanamide) [1] and 2,4,6-tris[bis(1H-tetrazol-5-yl)amino]-1,3,5-triazine [2]. The compound 2 is the first example for compounds having six tetrazole units on a triazine ring.

    • Nitrogen-rich compounds: s-triazine and tri-s-triazine derivatives as high energy materials

      MUDDAMARRI HANUMANTHA RAO VIKAS D GHULE KRISHNAMURTHI MURALIDHARAN

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      This article describes the syntheses, characterization, and energetic properties of 4, 6-diazido-N,N-dimethyl-1, 3, 5-triazin-2-amine and 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine. Also, this paper emphasizes the insensitive and thermally stable energetic molecules like melem, melemammonium perchlorate mixture, and hydrazinium cyamelurate. All these compounds possess good energetic properties viz., the heat of formation and heat of combustion.

      Synthesis and characterizations and energetic properties of 4, 6-diazido-N, N-dimethyl-1, 3, 5-triazin-2-amine (3); 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine (4) and hydrazinium cyamelurate (10) are described. The thermal stabilities, energetic properties and sensitivity parameters are compared with standard high-energy materials. (i) Syntheses and characterization of 4, 6-diazido-N, N-dimethyl-1, 3, 5-triazin-2-amine (3); 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine (4) and hydrazinium cyamelurate (10) are described. (ii) Experimental energetic properties and sensitivity parameters of these compounds were discussed.

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