T Arumuganathan
Articles written in Journal of Chemical Sciences
Volume 120 Issue 1 January 2008 pp 95-103
T Arumuganathan A Srinivasarao T Vijay Kumar Samar K Das
An inorganic−organic hybrid material, [HMTAH]2[{Zn(H2O)5}{Zn(H2O)4}{Mo7O24}].2H2O (
Volume 120 Issue 3 May 2008 pp 297-304
T Arumuganathan A Srinivasa Rao Samar K Das
An inorganic-organic hybrid material, [2-AmpH]4[Mo8O26] (
Volume 123 Issue 2 March 2011 pp 229-239
Polyoxometalates: Toward new materials
A Srinivasa Rao T Arumuganathan Vaddypally Shivaiah Samar K Das
This article describes an account of some of our polyoxometalate (POM)-based research, we have been doing in our laboratory last several years. There are several well-defined POM cluster anions, that are structurally characterized. We have chosen Anderson-type of heteropolyanion [Al(OH)6Mo6O18]$^{3−}$ and explored its linking propensity in different dimensions using `s', `d' and `f' block elements as linkers.We have demonstrated how a lanthanide linker provides a new pathway in forming a two-dimensional linked {As8V14} system [{Ln(H2O)6}2As8V14O42(SO3)]$_n$.8nH2O, that is derived from discrete {As8V14} cluster containing compound (NH4)6[As8V14O42(SO3)]. A polyoxometalate compound has been described in which a reduced tungstovanadate-heteropolyanion clusters get linked via capped V = O groups into one-dimensional chains. All these systems have already been reported elsewhere. The last portion of this article will be described by a new system [3-ampH]6[V10O28]$\cdot$2H2O having discrete molecular structure and extended supramolecular structure.
Volume 132, 2020
All articles
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode
© 2021-2022 Indian Academy of Sciences, Bengaluru.