Articles written in Journal of Chemical Sciences
Volume 126 Issue 5 September 2014 pp 1265-1273 Special issue on Chemical Crystallography
Thermal stability and thermal expansion of bromo trimer synthon mediated hexagonal inclusion compounds of 2,4,6-tris(4-bromophenoxy)-1,3,5-triazine (BrPOT) with dichloromethane (DCM), tetrahydrofuran (THF) and hexamethyl benzene (HMB) and also the guest-free form of BrPOT are reported. Each of these three guests produced two concomitant inclusion compounds with BrPOT. The thermal stability of the solvate lattice increases with decreasing cavity size. The channel network of the DCM inclusion compound is stable only for a few seconds at room temperature outside the mother liquor, whereas the cage network of the DCM solvate is stable for months under similar conditions. Thermal expansions of the lattices depend upon the network, guest content as well as the type of guest molecules. The guest-free form exhibits the least thermal expansion in this series of systems.
Volume 128 Issue 2 February 2016 pp 207-216 Regular Articles
Two analogous tripodal ligands, namely, 1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-triethylbenzene (
Volume 135, 2023
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