Articles written in Journal of Chemical Sciences
Volume 126 Issue 1 January 2014 pp 141-145
Selective hydrogenation of maleic anhydride over Pd/Al2O3 catalysts prepared via colloid deposition
Hongjing Yuan Chunlei Zhang Weitao Huo Chunli Ning Yong Tang Yi Zhang Dequan Cong Wenxiang Zhang Jiahuan Luo Su Li Zhenlu Wang
Pd/Al2O3 catalysts were prepared via colloid deposition and the performance of the catalysts was examined in the selective hydrogenation of maleic anhydride to succinic anhydride. When the reaction was carried on in a batch system with 1,4-dioxane as the solvent (353K and 1.0MPa), high conversion of maleic anhydride (>98%) and high selectivity (>99%) for succinic anhydride were observed after 5 h. The as-prepared Pd/Al2O3 catalyst also showed excellent performance in solvent-free system and fixed-bed systems. The maleic anhydride (MA) conversion was greater than 98%, and high selectivity (>99%) for succinic anhydride was obtained after 1600 h in a fixed bed reacter. The results showed that the activity of the Pd/Al2O3 catalysts was excellent due to its high active surface area.
Volume 135, 2023
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode