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- Saikat Kumar Seth
  
  Articles written in Journal of Chemical Sciences
- Volume 127 Issue 6 June 2015 pp 1057-1065 Regular Articles
  
  N, N′-Olefin functionalized Bis-Imidazolium Pd(II) chloride N-Heterocyclic carbene complex builds a supramolecular framework and shows catalytic efficacy for `C–C' coupling reactions
  
  Gourisankar Roymahapatra Tapastaru Samanta Saikat Kumar Seth Ambikesh Mahapatra Shyamal Kumar Chattopadhyay Joydev Dinda
  
  More Details Abstract Fulltext PDF
  
  The ligand 3,3′-(𝑝-phenylenedimethylene)bis{1-(2-methylallyl)} imidazolium bromide (1) and its Palladium(II) N-heterocyclic carbene (NHC) complex (3) has been synthesized and characterized by several spectroscopic techniques and the solid-state structure of 3 has been determined by single crystal X-ray diffraction studies. The Pd(II) complex possesses ring head to tail 𝛱–𝛱 stacking interactions (3.767 A$^{\circ}$) through imidazole rings. Complex 3 catalyzes Suzuki-Miyaura `C–C' coupling reaction. DFT calculations have been used to understand the HOMO/LUMO energy and hence the stability and reactivity of Pd(II) complex in syn and anti-configuration.

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