S N Bhat
Articles written in Journal of Chemical Sciences
Volume 89 Issue 2 April 1980 pp 139-144 Physical and Theoretical
Surface tension measurements can be used to investigate molecular complex formation in liquid solutions for strong and weak complexes. The association constant and epthalpy for triethylamine-iodine, hexamethylbenzene-tetracyanoethylene and ethanol-iodine in cyclohexane are 4·55×103, 218 and 0.93M−1 at 25° C and 12·5, 7·7 and 5·1 kcal/mol respectively. These values compare well with those reported in the literature by other methods.
Volume 94 Issue 3 June 1985 pp 461-466 Physical and Theoretical
The viscometric method can be conveniently used for studying the interaction between weakly interacting systems. The systems studied are: methanol-acetone, ethanol-acetone,
Volume 101 Issue 1 February 1989 pp 89-91 Rapid Communications
The absorption maximum of the3π1-1∑+ transition of the iodine molecule in cyclohexane is found to be at 689 nm. Derivative spectroscopic evidence for the blue shift of the above band in complexed iodine has been provided for the first time.
Volume 103 Issue 1 January 1991 pp 69-76 Physical and Theoretical
A conductometric titration technique has been used for determining the stoichio-metry of charge-transfer complexes which ionise in polar media. The systems studied are: Iodine complexes of acetone, methyl ethyl ketone,
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