SARAT CHANDRA PATRA
Articles written in Journal of Chemical Sciences
Volume 131 Issue 3 March 2019 Article ID 0024
The pyridylhydrazone ligand incorporating a pendant pyrene moiety HL has been synthesized starting from 2-hydrazinopyridine and its coordinating behaviour towards rhodium(III) have been scrutinized. The complex of type [RhL(PPh3)2Cl2], incorporating five-membered chelate ring has been isolated and the structure has been authenticated by single-crystal X-ray diffraction study. The ligand exhibits an oxidative response at ~1.2 V upon coordination with rhodium(III) and the optoelectronic properties as well as theoretical exploration have been performed by the density functional theory (DFT) as well as time-dependent density functional theory (TD-DFT) analyses.
Volume 134, 2022
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