SABEEL M BASHEER
Articles written in Journal of Chemical Sciences
Volume 130 Issue 11 November 2018 Article ID 0153
The N,N'-Bis(salicylidene)-2-hydroxy-phenylmethanediamine (BSHPMD) was synthesized and characterized by IR, UV-Vis and 1H NMR spectroscopic techniques. The single crystal X-ray diffraction studies reveal that the compound had a monoclinic crystal system with C2/c space group. The cation recognizing profile of the receptor BSHPMD was explored by UV-Vis and fluorescence spectroscopic methods. The receptor was found to recognize selectively Al3+ and Zn2+ ions over a panel of other metal ions such as Na+ , Mg2+ , Ca2+ , Mn2+ , Co2+ , Ni2+ , Cu2+ , Sr2+ , Cd2+ , Ba2+ , Hg2+ and Pb2+ . The Job’s plot analysis reveals that BSHPMD binds with Al3+ and Zn2+ in 1:1 stoichiometry ratio. The binding constants of the receptor for Al3+ and Zn2+ were 2.13 × 103 and 16.23 × 103 M-1 , respectively. The detection limit for Al3+ and Zn2+ is 10.04 × 10-8 and 4.98 × 10-8 M, respectively. The NMR titration and IR titration studies reveal the sensing mechanism of BSHPMD. The multi-ion detection of BSHPMD is used to construct NAND and OR molecularlogic gates. Hirshfeld surface analysis based on DFT method with 3-21G as basis set is used to calculate various intermolecular interactions. Fingerprint plots are made to find out the percentage of different types of interactions.
Volume 134, 2022
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode