Articles written in Journal of Chemical Sciences
Volume 93 Issue 2 March 1984 pp 157-164 Organic
The kinetics of oxidation of
Volume 100 Issue 6 December 1988 pp 459-462 Inorganic and Analytical
The preparation of a novel nickel trihydroxy isocyanate, along with its distinguishing physicochemical characteristics has been reported for the first time.
Volume 101 Issue 2 April 1989 pp 111-114 Inorganic and Analytical
Precipitation from a homogeneous solution of aluminium nitrate by neutralisation using urea in presence of succinic acid leads to the formation of a well-defined alumina precursor, basic aluminium succinate, which on calcination yields microspheroidal γ-alumina with excellent free-flowing characteristics.
Volume 102 Issue 3 June 1990 pp 418-462
Bhaskar G Maiya S M S Chauhan P Bhyrappa V Krishnan P K Bhardwaj Sabyasachi Sarkar Krishna B Pandeya Pavan Mathur Akhil R Chakravarty Birinchi K Das Digambar V Behere Sandeep Modi Samaresh Mitra Sandeep Modi Digambar V Behere Samaresh Mitra Anil Saxena Sandeep Modi Digambar V Behere S Mitra Shyamalava Mazumdar Okhil K Medhi Samaresh Mitra Shyamalava Mazumdar Samaresh Mitra Anup Madan Sandeep Modi Anil Saxena Digamber V Behere S Mitra T Pandiyan M Palaniandavar K L Narayanan H Manohar R Ramaraj C C Thomas S Rajagopal T Rajendra C Srinivasan P Ramamurthy R Roy M C Saha S Panchanan P S Roy C Balagopalakrishna M V Rajasekharan B V Agarwala S Hingorani G A Nagena Gowda Y S Ramaswamy R Halesha N M N Gowda G K N Reddy G C Saxena K L Gupta P Srivastava V D Gupta M Ray R N Mukherjee R N Mohanty K C Dash Ramesh Kapoor S Yadav V Sood P Kapoor B N Anand R Bains Usha K Aggarwal P Garge R Chikate S Padhye J M Savariault P De Loth J P Tuchgues V K Jain M A Vaidya S C Jain S Kalyan Kumar Harkesh B Singh K M Mangaonkar D N Patkar N K Jha Pankaj Sharma S K Date C E Deshpande S D Sathaye S B Deshpande H S Potdar V S Darshane A C Dash R K Nanda N N Das S Gangopadhyay P Banerjee S K Kulshreshtha P S Zacharias N Arulsamy T Ramasami V Subramanian B U Nair M Kanthimathi G Sundararajan V Shivasubramanian R G Bhattacharya S Biswas J Armstrong E M Holt A P Koley
Volume 103 Issue 5 October 1991 pp 637-643 Organic
The oxidation of 4,4′-disubstituted diphenyl sulphoxides by potassium permanganate on Hammett type correlations give a small positive ρ value (0.34). This is in contrast to the oxidation of aryl methyl sulphides (ρ = −1.36) by the permanganate ion. On the basis of rate data a mechanism of nucleophilic attack of MnO4− on the substrate has been proposed.
Volume 104 Issue 1 February 1992 pp 9-13 Inorganic and Analytical
The quenching rate constants,
Volume 104 Issue 6 December 1992 pp 762-790
J Basu K K Rohatgi-Mukherjee S Chatterjee S Sarkar S N Bhattacharyya G K Dasmahapatra Thomas Wolff Gunther Von Bunau S N Dhawan Dipankar Sen Subhash Ch Bera S C Gupta N S Yadav Manabendra Sahu Manjubikash Saha V Masilamani D Sastikumar Pradipta Kumar Behera Ashok Kumar Mishra S Muthusamy V T Ramakrishnan P Ramamurthy S Sampath R Narayan M C Durai Manickam C Srinivasan K Pitchumani M Roja S Rajagopal Reba Ray Samaresh Mukherjee A Samanta E Natarajan S Selvaraj P Natarajan S S Talwar K Viswanathan P Natarajan Aruna Dhathathreyan K S Dhathathreyan Basanti Biswal Pill-Soon Song S Das M Muneer A Haridas V B Manilal R Jayakumar T Ramasami M Julliard M Chanon P N Joshi U C Biswal C L Joshy E Purushothaman Bhaskar G Maiya S Ganesan B Nagarajan V Narayanan Prasanna Mohanty V Shubin S D S Murthy N V Karapetyan R Ramaraj K V Gobi V Gomathi Sankareswari S Ranganayaki K Bahadur Sajal Kumar H R Sonawane D G Kulkarni N R Ayyangar N Sukumar T V Venkitachalam A S Rao S I Ali Harpal Kaur V Anbalagan T S Srivastava Awadhesh Kumar P K Chowdhury K V S Rama Rao J P Mittal N Balasubramanian S Balasubramanian G B Dutt S Doraiswamy Bidyut Kumar Manna K K Rohatgi-Mukherjee A Chandra B Bagchi S Arunachalam J R Devadason T Dhanasekaran K Joseph Prabahar Lizamma Mathew V Ramakrishnan J Rajaram V R S Rao P Narayanan V N Sivasankara Pillai K I Priyadarsini T Rajendran M Palaniandavar M Kaneko A Kira M S Sidhu Arti Chopra Barinder Gill Thomas Baby V P N Nampoori
Volume 106 Issue 3 June 1994 pp 645-653
The rate of electron transfer (ET) in a variety of chemical and biological processes is influenced by factors like the free energy change (†G), the donor-acceptor electronic coupling and the medium. The effect of donor-acceptor electronic coupling on the rate of photoinduced intermolecular electron transfer is considered by taking Ru(II) and Cr(III) metal complexes in the excited state as electron acceptors and organic compounds as electron donors. The electronic coupling between the donor and acceptors depends strongly on donor-acceptor distance. The electron transfer distance is varied by introducing alkyl groups of different sizes either on the bipyridine ligand of the metal complex or on the quencher. The semiclassical theory of electron transfer expresses kET as the product of a nuclear and an electronic transmission coefficient (
Volume 112 Issue 3 June 2000 pp 410-410
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