Articles written in Journal of Chemical Sciences
Volume 89 Issue 1 February 1980 pp 65-68 Physical and Theoretical
The oscillation characteristics, investigated by potentiometry, of the bromate-Mn(II)/Ce(III)-malic acid system are presented. The induction period characteristic of the oscillatory system is analysed. The results are compared with the malonic acid and citric acid systems and are correlated with the difference in the rate of bromide production, proposed as the control intermediate.
Volume 97 Issue 5-6 December 1986 pp 581-586 Physical and Theoretical
Studies on the deposition and dissolution of copper from 0·5 M sulphuric acid solutions onto glassy carbon (GC) using potential sweep techniques indicated that an additional peak occurs at higher positive potentials than the bulk stripping peak. This peak is identified as due to the stripping of underpotential deposited (UPD) copper. Results of investigations on the effect of sweep rate, deposition potential and time of deposition on the peak characteristics of UPD and bulk deposited copper are also reported.
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