Articles written in Journal of Chemical Sciences
Volume 103 Issue 5 October 1991 pp 655-666 Physical and Theoretical
Thermal, spectroscopic and electrical properties of lead pyrophosphate glass prepared by melt quenching have been examined. A model based on the structural disproportionation of the P2O74− ions has been proposed and is shown to consistently explain all the observations. The equilibrium of various anionic species has been discussed on the basis of their electronegativities which are in turn related to their basicities.
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