Journal of Chemical Sciences | Indian Academy of Sciences

1. Home
2. Journals
3. Journal of Chemical Sciences
- Rajdip Dey
  
  Articles written in Journal of Chemical Sciences
- Volume 125 Issue 3 May 2013 pp 661-666
  
  Synthesis, crystal structure and photo luminescent property of a 3D metal-organic hybrid of Cd(II) constructed by two different bridging carboxylate
  
  Biswajit Bhattacharya Rajdip Dey Debajyoti Ghoshal
  
  More Details Abstract Fulltext PDF
  
  A solvothermal reaction of cadmium (II) nitrate with succinic acid and isonicotinic acid creates a novel 3D metal-organic framework, [Cd₃(isonicotinate)₂(suc)₂]$_n$(1). Single crystal X-ray structure determination reveals that complex 1 posses two crystallographically independent Cd(II) centres. The succinate anion acts here as a heptadented ligand and binds five Cd(II) centre simultaneously. The heptacoordinated Cd(II) centres are oxo-bridged by succinate moiety and the hexacoordinated metal centres are terminally connected through four different succinate moiety to make the overall 2D sheet arrangement. In unit cell, the ratio of hexadented Cd(II) and heptadented Cd(II) is 1:2. The new compound was also characterized by luminescence spectra and compared with the luminescence spectra of the pure isonicotinic acid.

Journal of Chemical Sciences

Volume 135, 2023
All articles
Continuous Article Publishing mode

Journal of Chemical Sciences | News
- Editorial Note on Continuous Article Publication
  
  Posted on July 25, 2019
  
  Click here for Editorial Note on CAP Mode
  
  TOP CITED ARTICLES 2019-2020

© 2022-2023 Indian Academy of Sciences, Bengaluru.

Contact | Site index