• R Varadarajan

      Articles written in Journal of Chemical Sciences

    • Dielectric studies of solute-solvent interactions in mono-alcohol systems

      R Sabesan R Varadarajan M Sargurumoorthy

      More Details Abstract Fulltext PDF

      Kirkwood-Fröhlich's linear correlation factor of dielectric polarisation of propan-2-ol, butan-1-ol, 3-methylbutan-1-ol and phenyl carbinol in solutions with cyclohexane, carbon tetrachloride and benzene as solvents which gives clue on the dipole orientation of the molecular aggregates of the alcohols is reported. The kinetic process responsible for the dielectric behaviour of these alcohols is analysed on the basis of significant structure model of associated liquids. Eyring's interaction parameterG* is influenced by the nature of the solvent and has been interpreted with regard to the changes in the dipole interaction of the solute domains in the solvent environment.

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