• R M P Jaiswal

      Articles written in Journal of Chemical Sciences

    • Vibrational spectra and thermodynamic functions of allyl acetate

      Bhadur Singh R Prasad R M P Jaiswal

      More Details Abstract Fulltext PDF

      Raman spectrum of allyl acetate molecule has been photographed in liquid phase using 4358 Å line of mercury arc as the exciting line. Infrared absorption spectrum of the molecule has been recorded in liquid phase in the frequency range 200–4000 cm−1. Both the spectra have been analysed to identify the fundamental frequencies. AssumingCs symmetry, the observed fundamental frequencies have been assigned to various modes of vibration and compared with the frequencies of allyl halides and acetic acid. On the basis of present assignments of fundamental vibrational frequencies and assumed approximate structural parameters of the molecule, thermodynamic functions have been computed.

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