Articles written in Journal of Chemical Sciences
Volume 130 Issue 6 June 2018 Article ID 0061
Restricted rotation about the C(1)-N single bond in N, N-disubstituted 1-aminoanthracenes has been investigated. The synthesis, isolation and characterization of diastereomers arising out of the hindered rotationabout the CSP2-NSP2 single bond has been demonstrated. With unsymmetrical substituents on the Nitrogen atom,preferred conformations about the C(1)-N bond were observed.
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