-
- Home
- Journals
- Journal of Chemical Sciences
-
Palani Sasikumar
Articles written in Journal of Chemical Sciences
-
-
Volume 118 Issue 6 November 2006 pp 455-462
Stannoxanes and phosphonates: New approaches in organometallic and transition metal assemblies
Vadapalli Chandrasekhar Kandasamy Gopal Loganathan Nagarajan Palani Sasikumar Pakkirisamy Thilagar
Phosphonate ligands, [RPO3]2-, are extremely versatile in the assembly of multi-tin and multi-copper architectures. We have used organostannoxane cores for supporting multi-ferrocene and multi-porphyrin peripheries. The copper-metalated multi-porphyrin compound is an excellent reagent for facile cleavage of DNA, even in the absence of a co-oxidant. Reaction of
t -BuPO3H2 with Cu(C104)2. 6H2O in the presence of 2-pyridylpyrazole (2-Pypz) leads to the synthesis of a decanuclear copper (II) assembly. -
Volume 120 Issue 1 January 2008 pp 105-113
Multi-functional architectures supported on organostannoxane scaffolds
Vadapalli Chandrasekhar Palani Sasikumar Puja Singh Ramalingam Thirumoorthi Tapas Senapati
Organostannoxane cages and aggregates of well-defined composition and structure can be prepared by the reactions of organotin oxides or organotin oxide-hydroxides with protic acids. The utility of this strategy for the preparation of dendrimer-like molecules containing a stannoxane core and a functional periphery is described.
-
-
Journal of Chemical Sciences
Volume 135, 2023
All articles
Continuous Article Publishing mode
-
Journal of Chemical Sciences | News
-
Editorial Note on Continuous Article Publication
Posted on July 25, 2019Click here for Editorial Note on CAP Mode
-