• PILAR GARCIA-ORDUNA

      Articles written in Journal of Chemical Sciences

    • Cyclopentadienyl iron dicarbonyl styrene chalcogenosulfonates: synthesis and structure of CpFe(CO)2SeSO2CH=CHPh

      MOHAMMAD EL-KHATEEB ALAA AL-MOMANI PILAR GARCIA-ORDUNA FERNANDO J LAHOZ

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      In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)2SeSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)2SeSO2CH=CHPh (2) featuring styrene moiety. 1and 2 are obtained by electrophilic attack of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) on the sulfuratom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized byelemental analyses, IR, 1H-, 13C{1H}-NMR, UV–Vis spectroscopy and the structure of 2 is determined byX-ray crystallography.

      In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)2SeSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)2SeSO2CH=CHPh (2) featuring styrene moiety. 1 and 2 are obtained by electrophilic attack of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se; x = 1) on the sulfur atom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized by elemental analyses, IR, 1H-, 13C{1H}-NMR, UV–Vis spectroscopy and the structure of 2 is determined by X-ray crystallography..

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