P V Ragini
Articles written in Journal of Chemical Sciences
Volume 113 Issue 4 August 2001 pp 343-350
With the aim of finding a suitable electrocatalyst for the efficient reduction of carbon dioxide, the electrochemistry of nickel (II) complex of 1,3,6,9,11,14-hexaazatricyclo [12·2·1·1] octadecane was studied using cyclic voltammetry (CV) and controlled-potential electrolysis (CPE) techniques in the presence and absence of CO2 in 100% H2O, CH3CN-H2O mixtures (20–100%) and DMF-H2O (70–100%) mixtures. The efficiency of this process is determined using the coulometry technique. CO is the major product in the gaseous phase and HCOOH the sole product formed in the solution phase.
Volume 132, 2020
Continuous Article Publishing mode
Click here for Editorial Note on CAP Mode