• P Sivaprasad

      Articles written in Journal of Chemical Sciences

    • Conductance behaviour of HCl in water-ethylene glycol, water-diethylene glycol and ethylene glycol-diethylene glycol mixtures

      P Sivaprasad C Kalidas

      More Details Abstract Fulltext PDF

      The conductance behaviour of HCl in water-ethylene glycol, water-diethylene glycol and ethylene glycol-diethylene glycol mixtures was investigated in the complete range of solvent compositions of 25°C by applying the three-parameter conductance equation. No appreciable association of the acid was observed in any of the mixed solvents. The large decrease ofΛ0 andΛ0η0 of the acid in the early and end composition region of the mixed solvents has been attributed to the drastic structural changes brought about by the addition of the organic component in the aqueous solvent mixtures and by the addition of diethylene glycol in the case of ethylene glycol-diethylene glycol mixtures.

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