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P S Radhakrishnamurti
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Volume 88 Issue 3 June 1979 pp 163-170 Physical and Theoretical
Kinetics of ruthenium(III)-catalysed oxidation of aromatic aldehydes by alkaline ferricyanide
P S Radhakrishnamurti B R K Swamy
The ruthenium(III)-catalysed ferricyanide oxidation of aromatic aldehydes in aqueous alkaline medium follows a zero order kinetics with respect to ferricyanide. The order with respect to Ru(III) is unity. The variation of substrate concentration follows Michaelis-Menton type of kinetics. The dependence on alkali is fractional below 0.05 M and tends to be independent above 0.05 M. The reaction proceeds through the reversible complexation between Ru(III) and the hydrated aldehyde, which decomposes in a rate determining step, giving the products. The structure reactivity relationship has been analysed in the light of Hammett’s plot.
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Volume 88 Issue 4 August 1979 pp 333-333 Erratum
Proceedings of the Indian Academy of Sciences—Section A—Volume 88–1979
V C Jyothi Bhasu D N Sathyanarayana C C Patel R Namasivayam S Nagarajan K Subramanyam Reddy P R Naidu P N Nandi Reddy D A Deshpande V G Kher T Manimaran M Natarajam V T Ramakrishnan N S Navaneetham S Soundararajan Wahid U Malik R N Goyal Sudha Tyagi Gobinda Basu B D Mali L D Pethe M S Ramachandran U Chandra Singh N R Subbaratnam V K Kelkar P S Radhakrishnamurti B R K Swamy B R K Swamy S P Gupta P Singh K V Sane R P Saxena P K Srivastava Balawant S Joshi Vinod R Hegde
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Journal of Chemical Sciences
Volume 135, 2023
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