• P Gautam

      Articles written in Journal of Chemical Sciences

    • Coordination aggregation of mesoaryl substituted porphyrins

      P Gautam V Krishnan

      More Details Abstract Fulltext PDF

      Synthesis of the free-basetetrakis (3′-nitro/aminophenyl), (H2TNP/ H2TAP) has been accomplished and its coordination behaviour towards Mg(II), Co(II), Zn(II) and Ag(II) ions is investigated. Optical and magnetic resonance properties of the metal derivatives MTNP and MTAP reveal that the aminoporphyrins exist as aggregates in solution. The aggregation is promoted by the coordination of the peripheral amino groups to neighbouring metalloporphyrins. Possible structures of aggregated species are proposed from the model studies.

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