• Meganathan Thirumal

      Articles written in Journal of Chemical Sciences

    • A new form of MgTa2O6 obtained by the molten salt method

      Ashok K Ganguli Shikha Nangia Meganathan Thirumal Pratibha L Gai

      More Details Abstract Fulltext PDF

      Using molten salt route (with NaCl/KCl as the salt) we have been able to synthesize a new form of magnesium tantalate at 850°C. Powder X-ray diffraction data could be indexed on an orthorhombic unit cell with lattice parameters, ‘a’ = 15.36(1) Å, ‘b’ = 13.38(1) Å and ‘c’ = 12.10(1) Å. High resolution transmission electron microscopy and electron diffraction studies confirm the results obtained by X-ray studies. Energy dispersive X-ray spectroscopy helps ascertain the composition of MgTa2O6. The title compound shows a dielectric constant of ∼24 with a low dielectric loss of 0.006 at 100 kHz at room temperature. Dielectric constant is nearly unchanged with rise in temperature while the loss shows a very marginal increase (0.007 at 300°C).

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