Maruthai Kumaravel
Articles written in Journal of Chemical Sciences
Volume 126 Issue 3 May 2014 pp 711-716 Regular Articles
Maruthai Kumaravel Pawan Kumar Maravanji S Balakrishna
The bisphosphomide-based pincer complex [PdBr{2,6-{Ph2PC(O)}2(C6H3)}] (
Volume 128 Issue 2 February 2016 pp 201-206 Regular Articles
Chloro(triphenylphosphole)gold(I) - A selective Chemosensor for Cysteine
Maruthai Kumaravel Maravanji S Balakrishna
Photophysical studies of luminescent gold complex of triphenylphosphole has been described. Addition of biologically relevant thio compounds was found to quench its fluorescence in methanol solution. Based on this, a simple and selective luminescence sensing method for cysteine detection has been developed.
Volume 129 Issue 4 April 2017 pp 471-481 Regular Article
Hydrazone derivatives appended to diphenylphosphine oxide as anion sensors
MARUTHAI KUMARAVEL JOEL T MAGUE MARAVANJI S BALAKRISHNA
Phosphine substituted hydrazones with or without nitro substituents were synthesized and characterized by multinuclear NMR, FT-IR, UV-Vis spectroscopy and single crystal X-ray diffraction. The anion recognition properties of phosphine oxides {Ph₂P(O)C₆H₄CHNNHPh} (2) and {Ph₂P(O)C₆H₄CHNNHC₆H₃ (2,4-NO₂) ₂} (4) with anions (F⁻, Cl⁻, Br⁻, I⁻, CH₃COO⁻ and H₂PO⁻ ₄ ) were investigated. The selectivity towards these anions is attributed to the hydrogen bonding capability of the NH bond. Competitive titrations have shown that the binding ability of fluoride with 4 is not influenced by the presence of other anions.
Volume 135, 2023
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