Articles written in Journal of Chemical Sciences
Volume 113 Issue 5-6 October 2001 pp 671-680
Together with hydrotalcite-like layered double hydroxides, bivalent and trivalent metal hydroxides and their hydroxy salts are actually anionic clays consisting of positively charged hydroxide layers with anions intercalated in the interlayer region. The anionic clays exhibit anion sorption, anion diffusion and exchange properties together with surface basicity making them materials of importance for many modern applications. In this article, we discuss many different ways of making anionic clays and compare and contrast the rich diversity of this class of materials with the better-known cationic clays.
Volume 117 Issue 6 November 2005 pp 629-633
A mixed-metal hydroxysalt of formula Cu1.6Zn0.4(OH)3(OAc)·H2O has been synthesized by an acetate hydrolysis route. Acetate ions can be exchanged with simple inorganic anions such as chloride and nitrate, and organic anions such as benzoate and large surfactant anions such as dodecyl sulphate. Structures of these hydroxysalts are derived from that of Cu2(OH)3NO3·H2O with some of the Cu2+ ions being replaced by Zn2+.
Volume 131 Issue 11 November 2019 Article ID 0112
Nickel-zinc hydroxy acetates with varying amounts of octahedral zinc, Ni(3-x)Zn((3-x)(OH)8(OAc)2.mH2 O, with x varying from 0 to 2, have been synthesized. The crystallographic 'a' parameter increases linearly with octahedral zinc content in the series. While the thermal stability is almost the same for the entire series of compounds, the stability of the compound in the alkaline medium increases with a decrease in octahedral zinc content. The selectivity for chloride ion from a mixture of chloride and bromide ions increases linearly with an increase in octahedral zinc content.
Volume 132, 2020
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