MEHMET CIVAN
Articles written in Journal of Chemical Sciences
Volume 130 Issue 11 November 2018 Article ID 0152
NURAN ASMAFILIZ MEHMET CIVAN NESE UZUNALIOGLU ARDA ÖZBEN ZEYNEL KILIÇ HANDE KAYALAK LEYLA AÇIK TUNCER HÖKELEK
The Cl replacement reactions of N/N or N/O spirocyclic monoferrocenylcyclotriphosphazatrienes (1–5) with the piperidine resulted in the geminal-(6–10) and tetra-piperidinophosphazenes with monoferrocenyl pendant arm (11–15). The structures of all the new compounds were determined using spectroscopic techniques. The ultrathin Langmuir–Blodgett (LB) films of two compounds (3 and 12) were prepared. The characterization of the LB films using p-polarized grazing angle (GAIR) and horizontal attenuated total reflectance (HATR) techniques was carried out. The molecular and crystal structure of the compound 6 was examined using X-ray crystallography. In addition, the interactions between six compounds (6, 7, 11, 12, 14 and 15) and pBR322plasmid DNA were investigated by agarose gel electrophoresis
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