Articles written in Journal of Chemical Sciences
Volume 113 Issue 5-6 October 2001 pp 681-688
New metal-carbon clusters, M4C9+ (M = Ti, V), generated using a combined thermal arc discharge evaporation set-up, have been studied with quadrupole mass spectrometry. Reactivities of these clusters have been investigated by means of association reactions with H2O. Metal-carbon clusters of other compositions have also been studied. We speculate on the mechanism of formation of larger metal-carbon clusters.
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