Kusalendiran Visvaganesan
Articles written in Journal of Chemical Sciences
Volume 123 Issue 2 March 2011 pp 145-162
Mallayan Palaniandavar Kusalendiran Visvaganesan
Catechol dioxygenases are responsible for the last step in the biodegradation of aromatic molecules in the environment. The iron(II) active site in the extradiol-cleaving enzymes cleaves the C-C bond adjacent to the hydroxyl group, while the iron(III) active site in the intradiol-cleaving enzymes cleaves the C-C bond in between two hydroxyl groups. A series of mononuclear iron(III) complexes of the type [Fe(L)Cl3], where L is the linear 𝑁-alkyl substituted
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