Krishna P Bhabak
Articles written in Journal of Chemical Sciences
Volume 123 Issue 6 November 2011 pp 783-789
In this paper, the synthesis and characterization of some imidazole-based gold-selenolates are described. This study indicates that the nature of selenolate plays an important role in ligand exchange reactions in gold(I) selenolates. Furthermore, the reactivity of imidazole-based gold(I) selenolates toward nucleophiles such as selenols and phosphines is strikingly different from that of the $N,N$-dimethylaminobenzylamine-based gold(I) complexes. The presence of Se$\cdots$N non-bonded interactions in $N,N$-dimethylaminobenzylamine-based gold(I) complexes modulates the reactivity of Au(I) centre towards incoming nucleophiles.
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