K M LOKANATHA RAI
Articles written in Journal of Chemical Sciences
Volume 128 Issue 7 July 2016 pp 1033-1036 Regular Article
SUMANA Y KOTIAN NARAYANA U KUDVA N K M LOKANATHA RAI K BYRAPPA
A new series of 4,5-dihydroisoxazole-5-carboxylate derivatives were synthesized via [3+2] cycloaddition reaction between ethyl acrylate and nitrile oxide generated in situ in presence of Chloramine-T. The synthesized derivatives were characterized by Mass, IR and NMR Spectroscopy and their mesomorphic behavior were studied using DSC and Polarising Optical Microscopy.
Volume 129 Issue 1 January 2017 pp 67-73 Regular Article
Two homologous series of unsymmetrical alkylated chalcones and 3,5-diaryl isoxazoles, consisting of 20 members, with various n-alkyl bromides (n=2−7, 10, 12, 14, 16) have been synthesized and studied for their liquid crystalline property. Simple strategy was employed to achieve the target materials. Flexibilityin the synthesized molecules is provided by attaching straight alkoxy chains, where one terminal group is fixed and other terminal group is varied. The synthesized compounds were characterized on the basis of Mass, IR and NMR spectroscopy. The stability and the range of the mesophases increased with the length of the chain on the isoxazoles. The melting point, transition temperatures and enantiotropic liquid crystal morphologies were determined by polarizing optical microscopy (POM) in conjunction with a hot stage and by differential scanning calorimetry (DSC).
Volume 131 Issue 6 June 2019 Article ID 0046
SUMANA Y KOTIAN P M ABISHAD K BYRAPPA K M LOKANATHA RAI
A novel reagent for the synthesis of isoxazolines has been reported. Aryl aldoximes were made to react with alkenes in the presence of KIO3 as the oxidising agent. This new reagent has been useful as an oxidant in the synthesis of isoxazoline and its function is attributed to the generation of nitrile oxide, which is an important intermediate for the synthesis of the valuable heterocycle like isoxazoline
Volume 135, 2023
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