KUMARA SWAMY KOPPADI
Articles written in Journal of Chemical Sciences
Volume 130 Issue 8 August 2018 Article ID 0106
Ni/KIT-6 catalysts for hydrogenolysis of lignin-derived diphenyl ether
JYOTHI YADAGIRI KUMARA SWAMY KOPPADI SIVA SANKAR ENUMULA VENKATESHWARLU VAKATI SEETHA RAMA RAO KAMARAJU DAVID RAJU BURRI PUPPALA VEERA SOMAIAH
A series of mesoporous silica KIT-6 supported Ni catalysts were prepared by wet impregnation method and evaluated for the lignin-derived diphenyl ether hydrogenolysis under atmospheric pressure in the continuous process. All the catalysts were characterized by powder XRD, N2-physisorption, SEM, TEM, H2-TPR analysis H2-pulse chemisorption studies. Among the catalysts, 20-wt%-Ni/KIT-6 exhibited better activity and selectivity due to the well dispersion of Ni particles through uniform pore channel of KIT-6. 20Ni/KIT-6 shows consistent selectivity to aromatics with a decrease in conversion of diphenyl ether during the time on stream studies
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