Articles written in Journal of Chemical Sciences
Volume 127 Issue 4 April 2015 pp 635-641 Regular Articles
Synthesis of phosphorus containing polyethers and their lithium-ion conductivities for the potential use as solid polymer electrolyte (SPE) in high-energy density lithium-ion batteries have been described. Co-polymerization of butyl bis(hydroxymethyl)phosphine oxide with three different dibromo monomers were carried out to produce three novel phosphorous containing polyethers (
Volume 129 Issue 6 June 2017 pp 657-661 Regular Aricle
This paper describes the synthesis, characterization and energetic properties of tetrazole and triazine-based thermally stable, insensitive nitrogen-rich high energy density materials of N, N’, N”-(1,3,5- triazine-2,4,6-triyl) tris(N-cyanocyanamide)  and 2,4,6-tris[bis(1H-tetrazol-5-yl)amino]-1,3,5-triazine . The compound 2 is the first example for compounds having six tetrazole units on a triazine ring.
Volume 129 Issue 12 December 2017 pp 1853-1861 REGULAR ARTICLE
A versatile methodology for the production of organic surfactant-free metal chalcogenide microparticles consisting of nano crystallites at room temperature in a short time is described. The reaction of various metal sources with LiBH4 in the presence of either S or Se yielded their corresponding CuS, Cu₂S, CdS and Cu₂-zSe microparticles. These micron size particles are aggregates of nano crystallites. The reactivity of LiBH4 and supersaturated condition helped in the formation nanocrystals. The first observation of metal source dependent morphology of particles produced under identical reaction condition is also discussed. The morphology of CuS particles obtained in these reactions was varying with the change of metal source used in the reaction. Interestingly, the reactions producing metal chalcogenide microparticles also yielded borane (BH₃) as a side product.
Volume 133 All articles Published: 5 February 2021 Article ID 0013
This article describes the syntheses, characterization, and energetic properties of 4, 6-diazido-N,N-dimethyl-1, 3, 5-triazin-2-amine and 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine. Also, this paper emphasizes the insensitive and thermally stable energetic molecules like melem, melemammonium perchlorate mixture, and hydrazinium cyamelurate. All these compounds possess good energetic properties viz., the heat of formation and heat of combustion.
Synthesis and characterizations and energetic properties of 4, 6-diazido-N, N-dimethyl-1, 3, 5-triazin-2-amine (3); 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine (4) and hydrazinium cyamelurate (10) are described. The thermal stabilities, energetic properties and sensitivity parameters are compared with standard high-energy materials. (i) Syntheses and characterization of 4, 6-diazido-N, N-dimethyl-1, 3, 5-triazin-2-amine (3); 2, 4, 6-tris (5-(3, 5-dinitrophenyl)-1H-tetrazol-1-yl)-1, 3, 5-triazine (4) and hydrazinium cyamelurate (10) are described. (ii) Experimental energetic properties and sensitivity parameters of these compounds were discussed.
Volume 133, 2021
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