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    • K V P Pa Van Kumar

      Articles written in Journal of Chemical Sciences

    • Volume 116 Issue 6 November 2004 pp 311-317 Full Papers

      Formation of phosphonates and pyrophosphates in the reactions of chlorophosphate esters with strong organic bases

      K V P Pa Van Kumar K Praveen Kumar M Vijjulatha K C Kumara Swamy

      More Details Abstract Fulltext PDF

      The compounds S(6-t-Bu-4-Me-C6H2O)2P(O)Cl (1), CH2(6-t-Bu-4-Me-C6H2O)2P(O)Cl (2) and (2,2′-C20H12O2)P(O)Cl (3) react with diazabicycloundecene (DBU) to give rise to, predominantly, the phosphonate compounds [S(6-t-Bu-4-Me-C6H6O)2P(O)(DBU)]+[Cl]− (4), [CH2(6-t-Bu-4-Me-C6H2O)2P(O) (DBU)]+[Cl]− (5) and [(2,2′-C20Hi2O2)P(0)(DBU)]+[Cl]- (6). The first two compounds could be isolated in the pure state. In analogous reactions of 1 and 2 with diazabicyclononene (DBN) or N-methyl imidazole, only the pyrophosphates [S(6-t-Bu-4-Me-C6H2O)2P(O)]2O (7) and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)]2O (8) could be isolated, although the reaction mixture showed several other compounds in the phosphorus NMR. A possible pathway for the formation of phosphonate salts is proposed. The X-ray crystal structures of4,7 and8 are also discussed.

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