I K Jain
Articles written in Journal of Chemical Sciences
Volume 90 Issue 4 August 1981 pp 309-316 Inorganic and Analytical
The complexing ability of vanadyl (V) chloride has been studied with N-2 (4, 5, 6 monosubstituted pyridyl)-N′-substituted thio urea ligands. The VOCl3 has been observed to form the six coordinated, diamagnetic complexes of the type VOCl3·L where L is a bidentate ligand molecule. The ligands are co-ordinated to the vanadium metal through pyridyl nitrogen and thioketo sulphur atoms.
Volume 91 Issue 1 February 1982 pp 15-19 Inorganic and Analytical
Vanadyl (V) chloride forms VOCl3 · L (L is a bidentate ligand molecule) type complexes with 1,5-disubstituted 2,4-dithiobiurets and 1,5-disubstituted-2-thiobiurets in carbon tetrachloride solution. Co-ordinations through sulphur atoms in case of 1,5-diaryl substituted 2,4-dithiobiurets and sulphur and oxygen in case of 1,5-diaryl substituted 2-thiobiurets have been proposed for these complexes.
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