-
- Home
- Journals
- Journal of Chemical Sciences
-
Gummadi Durgaprasad
Articles written in Journal of Chemical Sciences
-
-
Volume 127 Issue 2 February 2015 pp 295-305
Gummadi Durgaprasad Samar K Das
Compounds [Fe2{𝜇-pydt}(CO)6] (pydt = pyrazine-2,3-dithiolate) (
1 ), [Fe2{𝜇-qdt}(CO)6] (qdt = quinoxaline-2,3-dithiolate) (2 ), [Fe2{𝜇-ppdt}CO)6] (ppdt = pyrido[2,3-b ]pyrazine-2,3-dithiolate) (3 ), [Fe2{𝜇-pydt}(CO)5PPh3] (4 ), [Fe2{𝜇-qdt}(CO)5PPh3] (5 ) and [Fe2{𝜇-ppdt}(CO)5PPh3] (6 ) have been synthesized in order to model the active sites of `[FeFe]-hydrogenase’. Compounds1–6 have been characterized by routine spectral studies and unambiguously by single crystal X-ray crystallography. Supramolecular chemistry of compounds1–6 have been described in terms of intermolecular interactions, observed in their respective crystal structures. Electro-catalytic hydrogen evaluation studies (from acetic acid) have been performed using compounds1–6 as electro-catalysts. The mechanistic aspects of relevant electro–catalytic proton reductions have been discussed in detail.
-
-
Journal of Chemical Sciences
Volume 134, 2022
All articles
Continuous Article Publishing mode
-
Journal of Chemical Sciences | News
-
Editorial Note on Continuous Article Publication
Posted on July 25, 2019Click here for Editorial Note on CAP Mode
-