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- Gaetano A Tomaselli
  
  Articles written in Journal of Chemical Sciences
- Volume 125 Issue 4 July 2013 pp 869-873
  
  Binding of reactive organophosphate by oximes via hydrogen bond
  
  Andrea Pappalardo Maria E Amato Francesco P Ballistreri Valentina La Paglia Fragola Gaetano A Tomaselli Rosa Maria Toscano Giuseppe Trusso Sfrazzetto
  
  More Details Abstract Fulltext PDF
  
  In this contribution, the ability of simple oximes to bind a well-known nerve agent simulant (dimethylmethylphosphonate, DMMP) via hydrogen bond is reported. UV/Vis measurements indicate the formation of 1:1 complexes. ¹H-, ³¹P-NMR titrations and T-ROESY experiments confirm that oximes bind the organophosphate via hydrogen bond.

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