G ROBIN WILSON
Articles written in Journal of Chemical Sciences
Volume 128 Issue 8 August 2016 pp 1285-1290 Regular Article
Trichloroisocyanouric acid (TCCA)-functionalized mesoporous silica nanocomposites (SBA/TCCA) were synthesized and characterized for the acylation of indole. The uniform incorporation of TCCA inside the SBA-15 matrix was confirmed by standard characterization techniques (PXRD, Adsorption studies, FT-IR, etc.). The catalytic activity studies of SBA/TCCA nanocomposites for acylation of indole showed high selectivity (60–90%) of the 3-acetyl indole compared to homogeneous TCCA (50%). The advantage of solid support for higher selectivity is also explained.
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